Allylic Cations in Solvolysis . A Case of Non - Participation
نویسنده
چکیده
The rate constants and secondary deuterium Isotope ef'fects are measured in the solvo'lysis of various allyHc p-nitrobenzoates. The obtained results are explained by differences in inductive effects o>f vardous groups in the side-chain. These results are in keeping with the stepwise mechanism according to which neighboiring group nand n-paxticiipation is not revealed in the studied solvCJ!lytic reactions.
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